Cyclic silicones

Cyclic Silicone vs. Volatile Silicone

  1. Volatile silicones relate to materials that have a low heat of vaporization and the ability to select a desired vapor pressure; they therefore evaporate from the skin quickly, providing a dry feel. They can be linear or cyclic. Low viscosity silicone fluids are volatile but not cyclic. An example is 0.65 viscosity silicone fluid, sometimes.
  2. Cyclic silicones have been shown to involve the occurrence of silanols during biodegradation in mammals. The resulting silanediols and silanetriols are capable of inhibiting hydrolytic enzymes such as thermolysin , acetycholinesterase , however, the doses required for inhibition are by orders of magnitude higher than the ones resulting from the accumulated exposure to consumer products.
  3. Cyclic Silicones are under restriction in Europe and Canada for Environmental Toxicity and include cyclotetrasiloxane (D4), cyclopentasiloxane (D5), cyclohexasiloxane (D6), and cyclomethicone. There has been data presented that indicates that some of these chemicals may have reproductive toxicity and/or endocrine disruption concern
  4. D5. Decamethylcyclopentasiloxane, more commonly known as D5, contains five repeating units of silicon (Si) and oxygen (O) atoms in a closed loop, giving it a cyclic structure.. Where is it used? D5 is an odorless, colorless liquid mostly used as an intermediate or basic raw material in the production of silicone rubbers, gels and resins. When used as an intermediate during the manufacturing.
  5. AB Specialty Silicones launched a new line of silicone resin blends that combine unique carriers with trimethylsiloxysilicate (TMS) in late 2019. A notable addition to the product line was a cyclic-free blend, Andisil® MQ 2350, INCI Name: Dimethicone (and) Trimethylsiloxysilicate

silicones can continue to provide all the benefits and innovations for which they are used with confidence. Due to the specifics of silicone chemistry it is not possible to produce silicone polymers and silicone copolymers under industrial conditions with 'zero D4 / D5'. During polymerization a certain amount of cyclic siloxanes will remai Unlike dimethicones, which are linear siloxanes that do not evaporate, cyclomethicones are cyclic: both groups consist of a polymer featuring a monomer backbone of one silicon and two oxygen atoms bonded together, but instead of having a very long linear backbone surrounded by a series of methyl groups (which produces a clear, non-reactive, non-volatile liquid ranging from low to high. Siloxanes consist of silicon atoms linked via oxygen atoms, forming a cyclic or linear backbone structure. Each silicon atom bears one or several side chains, which may form cross-links and influence the properties of the polymer (e.g. phenyl side groups provide oxidative stability, aminopropyl sid No matter what your skin type, one of the ingredients I recommend avoiding is silicone. Or silicones, I should say—because these slippery ingredients go under dozens of different names, with new compounds being developed all the time.. That makes them hard to identify and even harder to avoid, as they've become the new normal in beauty formulations, from makeup to skincare to haircare

Silicone - Wikipedi

Related tags: Silicone, cyclic silicones, Formulation, ECHA, European union Specialty chemicals firm Innospec has developed a proprietary blend of low and high volatile silicones to replace D5 cyclic siloxane - an important move given the upcoming European ban, says its head of technical services for personal care Silicones are synthetic polymers with a silicon-oxygen backbone similar to that in silicon dioxide (silica), but with organic groups attached to the silicon atoms by C-Si bonds. The silicone chain exposes organic groups to the outside. Thus, despite having a very polar chain, the physical properties of silicones are similar to those of an alkane


What Are Silicones? Here's Everything You Need to Know

Silicone Chemistry Overview 2 By analogy with ketones, the name silicone was given in 1901 by Kipping to describe new compounds of the generic formula R 2 SiO. These were rapidly identified as being polymeric and actually corresponding to polydialkylsiloxanes, with the formulation These non-water soluble silicones are what are known as bad silicones. But, luckily, there are good silicones too that slow down the build-up process and that are indeed water-soluble. Plus, even if you are attached to the bad kind - after all, if something works for you and your hair, then get at it! - there are ways to combat the build-up before it happens Silicones are widely used in cosmetics, they are usually the reason why your skin feels so soft in the morning after applying your day cream, but silicones have been criticized for years : what is the danger or the risks for your skin ? hair 11) In normal silicates, each silicon atom is surrounded by . a) five oxygen atoms in a trigonal bipyramidal geometry . b) four oxygen atoms in a square planar geometry . c) four oxygen atoms in tetrahedral geometry . d) six oxygen atoms in octahedral geometry . 12) Which of the following is an example of cyclic silicate? a) Spodumene . b) Olivin of the restriction. D4, D5 and D6 may be impurities in silicone polymers, therefore the impact of a restriction on the uses of D4, D5 and D6, also includes an assessment of the impact on relevant uses of silicone polymers and if necessary action is taken to mitigate any significant impacts

Cyclosiloxanes Information Center - What are Cyclosiloxanes

  1. silicone containing formulations have a good spreadability. Ref.: AR 1 Depending on the product type, the concentration of D4 in formulations varies between 0.1-and 54%. It is common to use a blend of cyclosiloxanes D4, D5 and D6 in cosmetic products. Thus, products containing D4 may also contain D5 and D6. Ref.: AR
  2. cyclic silicones. FAQ. Medical Information Search. Select a category... Silicones Silicone Oils Silicone Elastomers Breast Implants Retinal Detachment Dimethylpolysiloxanes Vitrectomy Prostheses and Implants Foreign-Body Reaction Dental Impression Materials Siloxanes Granuloma, Foreign-Body Emulsions Polyurethanes Scleral Buckling Contact Lenses, Hydrophilic Materials Testing Cosmetic.
  3. Formulate Without Compromise By using the right blend of our cyclic-free silicones, it is possible to create the exact balance of properties your formulation requires. This is essential for giving hair and skin products the right feel. Our range of INNOSIL cyclic-free silicones is extremely versatile with plenty of options to choose from. We can [
  4. constant flow Column: HP-1 60 m x 0.25 mm x 0.25 µm film (or equivalent column) Oven: 50 °C (5

AB Specialty Silicones' new cyclic-free resin blend

  1. Siloxane polymers have been widely used in antimicrobial and nonfouling surfaces, but their use as solution-based antimicrobials is far more limited. Sauvet et al. 105 developed a postfunctionalizaton method to create quaternary ammonium-containing siloxane polymers (C14) (Figure 20).Homopolymers, as well as random and block copolymers with PDMS, were created by a combination of.
  2. o functional polymers have been used in rinse off conditioners, and silicone emulsions have been used in two‐in‐one conditioning.
  3. The key difference between silicone and siloxane is that silicone is a polymer material whereas siloxane is a functional group.. Although we use the terms silicone and siloxane interchangeably, they are very different from each other; a siloxane is a functional group while silicone is a substance containing this functional group

The ever-evolving Personal Care industry is soon to be faced with a regulatory requirement to formulate away from cyclic silicones and more recently the proposed legislation to eliminate the use of cyclopentasiloxane and cyclohexasiloxane from all personal care products Following this approach, a cyclic tetramer precursor of highly fluorinated silicones was prepared without the use of hydrosilylation or Grignard reactions. 29 A new method of the rational synthesis of cyclic and bicyclic siloxanes was described that exerts the control of reactions by exploiting the differences in reactivity of various functional groups of bifunctional silanes

  1. ECHA classifies cyclic siloxanes as SVHCs D4, D5 and D6 categorized as very persistent and very bioaccumulative; D4 also persistent, bioaccumulative and toxic; industry opposes to classification as substances of very high concer
  2. Silicone cyclics are useful building blocks in the synthesis of silicone fluids and resins. They can also be used as carriers and solvents in cosmetic applications. Product. Chemical Name. CAS #. GP-275. Octamethylcyclotetrasiloxane. 556-67-2
  3. Specialty Silicones; Siloxanes; Cyclic Siloxanes; Overview; Cyclic Siloxanes Product Functionality Product code CAS No. Product Tetramethyl-1-oxa-2,5-disilacycopentane: Functionality: Product code 9000000887: CAS No. 7418-20-4: Contact us: Product (3,3,3-Trifluoropropyl)methylcyclotrisiloxane
  4. When manufacturing silicone-based additives, the current state of technology involves the retention of certain cyclic siloxanes (D4, D5, D6) in the end product. A re-evaluation of the hazard potential of these substances at EU level dated June 27, 2018 means that some silicone additives now require additional labeling
  5. Cyclic silicones (or siloxanes) are frequently used as solvents for fragrance and essential oils, and also as carrier fluids for higher molecular weight silicones such as dimethicone and dimethiconol
  6. Pre-Order form for cyclic-silicones for Cosmetic and Personal Care Products. Name * First Name. Last Name. Email * Phone * (###) ### #### Organization * Other Alternatives Portfolios you are interested in? When available, I will pay for.
  7. Silicone polymers or polydialkylsiloxanes are an important class of inorganic polymers that find many industrial uses. They are known for their outstanding temperature and oxidative stability, excellent low temperature flexibility, and high resistance to weathering and many chemicals. These polymers also have low surface tension.

Siloxane - Wikipedi

Exploring new opportunities: cyclic silicone-free formulating. The ever-evolving Personal Care industry is soon to be faced with a regulatory requirement to formulate away from cyclic silicones and more recently the proposed legislation to eliminate the use of cyclopentasiloxane and cyclohexasiloxane from all personal care products Cyclic Siloxanes are commonly used in industrial and chemical manufacturing as delivery agents / carriers of a wide range of ingredients. Search info@andisil.com 847.599.776 all volatile silicones are not cyclic (for example MM). The term cyclomethicone refers to a structure; the term cyclomethicone refers to a physical property. Cyclomethicone is available in a variety of compositions. Pure D3, D4, and D5 ar Cyclomethicones (Volatile Cyclic Silicones) Cyclo‐2244 (D4), Cyclo‐2245 (D5) & Cyclo‐2345 (D5/D6 blend) Cyclomethicones are unmodified silicones that possess a cyclical structure rather than the chain structures of dimethyl silicones. Low heat of vaporization and the ability to select a desire

Arguably silicones and silicone derivatives are the most useful and versatile of all existing groups of cosmetic ingredients. They range in viscosity from volatile liquids to solid pastes and are used as emollients that provide unique sensorial properties, hair conditioning agents, emulsifiers and for the surface treatment of pigments These cyclic siloxanes were often known as 'flyers' - known to be very volatile , she said, and of concern from an environmental perspective. Details on the upcoming restriction were outlined in the recently published Annex XV Restriction Report for D4, D5 and D6 This chapter presents successively the polymerization of cyclic ethers, cyclic esters, cyclic amides, cyclosiloxanes and other cyclic silicon-based compounds, cyclic carbonates, and other cyclic monomers, i.e., cycloalkanes, cyclic sulfides, cyclic amines, cyclic ureas, depsipeptides, and cyclic phosphorus monomers This video is unavailable. Watch Queue Queue. Watch Queue Queu

Silicon microwires as anodes for Li-ion batteries may show good cycling performance over 100 cycles as anodes for Lithium ion batteries without significant capacity losses. The life time of the anode, however, strongly depends on the way the battery is charged. Overcharging or undercharging may have severe negative consequences Cyclic siloxanes (D4, D5, D6) are widely used in skin products. They improve skin sensory properties and alleviate dry skin, but there is still one report (published 2019), which regards their effects on the destruction of the skin barrier, by using fluorescence microscopy and attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR) The present invention relates to the use of a cosmetic composition containing, in a cosmetically acceptable medium, at least one non-crosslinked cyclic silicone copolymer and at least one solvent selected from linear silicones, cyclic silicones, hydrocarbons and mixtures thereof, for to improve the fixing and / or holding of skin makeup compositions Cyclics & Volatile Fluids for personal care provide transient skin emolliency and eventually dissipate leaving no residue. They are known for evaporation without cooling or irritation and are excellent carriers

7 Reasons to Avoid Silicones on Your Skin - The Skincare Edi

Silicone nipples and silicone bakewares were extracted using pressurised solvent extraction (PSE) and analysed using the GC-MS-SIM method. No linear siloxanes were detected in the silicone nipple samples analysed. The three cyclic siloxanes (D4, D5 and D6) were detected in all silicone nipple samples with concentrations ranging from 0.5 to 269. Protein denaturation induced by cyclic silicone. Sun L(1), Alexander H, Lattarulo N, Blumenthal NC, Ricci JL, Chen G. Author information: (1)Department of Bioengineering, Hospital for Joint Diseases, Orthopaedic Institute, New York, NY 10003, USA A sensitive, one-step sample preparation method for detection of volatile, low molecular weight (LMW) cyclic silicones hexamethylcyclotrisiloxane (D3), octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) in plasma and blood using gas chromatography coupled with mass spectrometry (GC/MS, SIM mode) is presented. In spiked experiments. Decamethylcyclopentasiloxane (D5) molecule. Cyclic silicone chemical, frequently used in cosmetics (deodorants, sunblocks, hair. Illustration about cyclopentamethicone - 19111845 Silicone in Everyday Life . Silicone is durable, easy to manufacture, and stable over a wide range of chemicals and temperatures. For these reasons, silicone has been highly commercialized and is used in many industries, including automotive, construction, energy, electronics, chemical, coatings, textiles, and personal care

Cyclic siloxane D4, D5, D6 ECHA ban alternative from Innospe

US5241097A US07/994,005 US99400592A US5241097A US 5241097 A US5241097 A US 5241097A US 99400592 A US99400592 A US 99400592A US 5241097 A US5241097 A US 5241097A Authority US United States Prior art keywords cyclic siloxanes producing cyclic alcohol alkane butanol Prior art date 1992-12-21 Legal status (The legal status is an assumption and is not a legal conclusion silicones is often used synonymously with siloxanes. The properties of the siloxanes and the silicone products depend on the length of the Si-O backbone, the chemical groups attached to the backbone and the presence of cross-links between the backbones. Silicone products are grouped into silicone fluids, elastomers and resins De très nombreux exemples de phrases traduites contenant cyclic silicone - Dictionnaire français-anglais et moteur de recherche de traductions françaises Cosmetic grade silicone is safe, that's a FACT. And if people spent more time researching FACTS, and less time getting hysterical over manipulated data, half-truths, and flat-out lies from fear-mongering activist groups, they'd understand silicone's incredible contribution to the cosmetic industry

Silicones are a family of compounds. You might have heard of silicone caulk. You certainly wouldn't want to put that in your hair. There are a variety of silicones from some that are pretty heavy' and prone to building up to some that are relatively light. One of the heavier silicones used in hair products is dimethicone or simethicone cyclic trimers , D [R 2 SiO] 4-5 cyclic tetramers and pentamers 1020-1010 the ring becomes larger (D 1090-1075 on Silicon, Germanium, Tin and Lead Compounds 1974, 1, 193. Si—N=C=O 2280 Trimethylsilylisocyanate has a very strong —N=C=O band at 2280 cm-1 The silicone nipples tended to have less cyclic. oligomers than the bakeware products. For example, the highest concentration of D6 in the bakeware. products was about 7000 mg/kg, while the maximum Volatile carrier for silicone elastomer gels, gum blends, and fluids ; Compatible with a range of cosmetic ingredients ; Further reduces the non-volatile content of silicone elastomer gels, gum blends, and fluids ; Delivers a silky feel within skin care applications ; Delivers enhanced spreadability and emolliency within skin care formulation

Silicones - Essential Chemical Industr

  1. Les silicones sont des ingrédients de synthèse qui se présentent sous la forme d'huiles et de gels à la texture plus ou moins épaisse. Pour les retrouver dans nos produits, ils figurent dans la liste des ingrédients sur le packaging, notamment sous les noms « dimethicone », « cyclopentasiloxane », « dimethiconol », « phenyl trimethicone », « amodimethicone.
  2. Reactive Silicones - Forging New Polymer Links coatings, membranes, cured rubbers and adhesives for mechanical, optical, silicones as well as physical property shortens product development time for chemists and engineers. Silicone Fluids - Stable, Inert Media available in viscosities ranging from 0.65 to 2,500,000 cSt
  3. Silicone bakeware is non-stick, and in fact, experts recommend you skip greasing silicon baking dishes, as they will function better without the grease, and will make cleanup easier as well. Compared to their plastic counterparts, silicone spatulas are the obvious choice: They are friendly on non-stick surfaces, and can handle the high heat of a stovetop
  4. A new method for the synthesis of main chain poly-imidazolium salts was developed from bisimidazole and silicon tetrachloride. These types of silicon-based poly-imidazolium salts are found to be among the most efficient metal-free heterogeneous catalysts (TOF = 90 h −1) for the fixation of CO 2 with epoxides into cyclic carbonates under metal- and solvent-free conditions
  5. It is a silicone that is easy to wash out of the hair and doesn ' t leave a heavy buildup. Look for products containing cyclomethicone. This is the most commonly used silicone in hair-care products, and it does everything silicone promises to do, but won't leave buildup on the hair. Dimethicone copolyol is water-soluble, too
  6. The silicones industry cooperates closely with regulatory agencies and expert scientific panels in North America, Chemical fate and transport in the environment of cyclic volatile methylsiloxanes, by S. Xu, F. Wania, Elsevier. D4, D5,.
Properties of Silicones

ECHA classifies cyclic siloxanes as SVHCs Food Packaging

Cyclic methylsiloxanes are used at high concentrations as an ingredient carrier for deodorants and antiperspirants, which account for half of the entire U.S. market for silicones in cosmetics. All silicones are derived from the element silicon (that's Si on the periodic table for those of us who slept during grade school science). Silicon oxide is a natural substance Cluster acrylic silicones having cyclic clusters . United States Patent 4760122 . Abstract: Novel polyorganosiloxane polymers having at least one terminal cyclic diorganosiloxane moiety containing a plurality of acrylic units of the formula ##STR1## wherein R 1 is H or lower alkyl; X is O, NH or S; and Y is a. OSTI.GOV Journal Article: Cyclic fatigue in silicon nitride ceramics. Cyclic fatigue in silicon nitride ceramics. Full Record; Other Related Researc

What Silicones Are In Cosmetics - Chemists Corne

Polydimethylsiloxane (PDMS), also known as dimethylpolysiloxane or dimethicone, belongs to a group of polymeric organosilicon compounds that are commonly referred to as silicones. PDMS is the most widely used silicon-based organic polymer due to its versatility and properties leading to many applications. It is particularly known for its unusual rheological (or flow) properties So, you can't use D4 or D5 silicones: What are the alternatives? By John Woodruff 10-Sep-2018. Ingredients. With the cosmetics industry searching for alternatives to commonly used silicones such as cyclomethicone and dimethicone, John Woodruff explores silicone replacements, silicone hybrids and other novel alternatives to more controversial material Author: Wiltshire, Georgina Created Date: 20160304115111 Silicones are truly jacks of all trades, capable of standing up to the toughest of requirements. Modern life would be inconceivable without silicones. And, thanks to the freedom for design - ing the silicone molecule, there are countless future applications still to come. We encounter silicones every day, though we hardly every notice them. 2,4,6,8 -Tertramethyl-2,4,6,8-tetravinylcyclotetrasiloxane (95% minimum) ; CAS # 2254-06-5. Avantor ®, a Fortune 500 company, is a leading global provider of mission-critical products and services to customers in the biopharma, healthcare, education & government, and advanced technologies & applied materials industries.Our portfolio is used in virtually every stage of the most important.

Eye Smooth™ | Eye Cream | MONAT Skincare Products

Selecting the perfect silicone for your formulatio

Silicone (polysiloxane) polymers can be classified as fluids, elastomers, and resins. Polymers of moderate molecular weight are fluids, while high molecular weight, slightly cross-linked polymers are elastomeric. Low molecular weight resins contain functional groups, usually hydroxyl, alkoxy, or chloro groups that undergo hydrolysis and/or condensation to form highly cross-linked structures Outgassing of Silicone Elastomers J. Rothka, R. Studd, K. Tate • and D. Timpe ARLON - Silicone Technology Division Bear DE 19701 800-635-9333 Abstract The performance advantages of silicone elastomers are widely known. Silicone provides unique characteristics that allow it to be used in a broad range of applications, includin

Silicones for Curly Hair: Good, Bad and the Ugly

Silicone Solvent - An Alternative Solvent for Dry Cleaning. The health risks of perchloroethylene as a dry cleaning solvent has spurred the demand of alternative solvents to replace the use of perc'. One the potential alternatives developed is based on a silicone -based solvent called decamethylcyclopentasiloxane (D5) Silicone Polymers Last updated; Save as PDF Page ID 1132; Superball Demonstration; Contributors; Silicone polymers, more properly called polysiloxanes, do not have carbon as part of the backbone structure. Although silicon is in the same group as carbon in the periodic table, it has quite different chemistry Dynamic production of cyclic siloxanes: octamethylcyclotetrasiloxane D4, decamethylcyclopentasiloxane D5 and dodecamethylcyclohexasiloxane D6 increases their concentrations in environment. It is considered that both environmental pollution and the usage of personal care products and cosmetics containing cyclic siloxanes can be the main source of the human exposure by transdermal route divinylsiloxanes or cyclic vinylsiloxanes. The system is usually prepared in two parts. By convention, the A part usually contains the platinum at a level of 5-10ppm, and the B part usually contains the hydride functional siloxane. Formulation of addition cure silicones must address the following issues

Silicones in cosmetics : the danger and risks for you and

Cyclic silicones include cyclotetrasiloxane (D4), cyclopentasiloxane (D5), cyclohexasiloxane (D6), and cyclomethicone. References: You can read more about it and the industry's stand by leading cosmetic markets increasing viscosity of the investigated silicone oils. Cyclic and linear siloxanes ≤D 20/L have been shown to migrate via gas phase in a simulated baking process (200°C, 1 h). In extracts of the investigated silicone elastomers exclusively cyclic siloxanes were detected • Etch rate of silicon as XeF 2 gas (not plasma) and Ar+ ions are introduced to silicon surface. Only when both are present does appreciable etching occur • Etch profiles can be very anisotopic, and selectivity can be good • Many different mechanisms proposed for this synergistic etching between physical and chemical components


Silicone fluids have unique properties because they are not products of petroleum or organic chemistry. They were the first, and are still the only, major class of polymers that are products of inorganic chemistry. Silicone fluids consist of a broad range of different materials with the following charac This application relates to cyclic siloxane compounds comprising the structural formula where a≧2 and b≧2, R is an alkyl group containing 1 to 4 carbon atoms, R1 is independently hydrogen or methyl, compositions comprising any of the above cyclic siloxanes and an additional silicone, emulsion compositions comprising any of the above cyclic siloxanes or the above composition, and a process. Cyclic vomiting syndrome is characterized by episodes of severe vomiting that have no apparent cause. Episodes can last for hours or days and alternate with symptom-free periods. Episodes are similar, meaning that they tend to start at the same time of day, last the same length of time, and occur with the same symptoms and intensity CYCLOMETHICONE Cyclomethicone is a mixture of low molecular weight volatile cyclic siloxanes, in varying proportions. It provides excellent stability and is an ideal carrier for color cosmetics, make-up, skin creams and hair care products divinylsiloxanes or cyclic vinylsiloxanes . The system is usually prepared in two parts . By convention, the A part typically contains the vinyl-containing silicone and the platinum catalyst at a level of 5-10ppm, and the B part usually contains the hydride functional siloxane

Sealnflex 720 gm Polyurethane BOSTIK - Tile Grout OnlineHair Products - MONAT Global - Monat Junior GentlePolymers | Special Issue : Ring-Opening Polymerization

and the generation of a new redox couple relating to the reduced silicon were observed in a cyclic voltammogram at Mo. Spectroscopic analyses confirmed the formation of a silicon layer from the reduction of SiO 2 NPs. Although the deposit was not continuous, XPS shows that it is silicon of good purity and XRD shows the pattern of crystalline. Gransurf 50C Cyclic-Free Silicone Emulsifier ; May 27, 2009; Gransurf 50C is an effective emulsifier for water-in-oil (w/o) emulsions. It is 50% active and uses a special grade of low viscosity dimethicone as the preferred new solvent choice Cyclic silicone silicone gum(Guangdong China), US $ 2 - 8 / Kilogram, Cyclic silicone silicone gum, Guangdong, China, 100%.Source from Guangzhou Yiming Chemical. Download this stock image: Decamethylcyclopentasiloxane (D5) molecule. Cyclic silicone chemical, frequently used in cosmetics (deodorants, sunblocks, etc) - DR6K9Y from Alamy's library of millions of high resolution stock photos, illustrations and vectors In the process of polymer, polysiloxane of different molecular weights can be produced by controlling the ending agent and the relative concentration of cyclic. Property&Application. Dimethylcyclosiloxane(DMC) is the main raw material of producing silicone rubber and silicone oil

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